script in root of WP
<?php
// Set $to as the email you want to send the test to.
$to = "you@yourdomain.com" ;
// No need to make changes below this line.
// Email subject and body text.
$subject = ' wp_mail function test ' ;
$message = ' This is a test of the wp_mail function: wp_mail is working ' ;
$headers = '' ;
// Load WP components, no themes.
define ('WP_USE_THEMES', false);
require('wp-load.php');
// send test message using wp_mail function.
$sent_message = wp_mail( $to, $subject, $message, $headers);
//display message based on the result.
if ( $sent_message ) {
// The message was sent.
echo 'The test message was sent. Check your email inbox.' ;
} else {
// The message was not sent.
echo 'The message was not sent!' ;
}
http://www.butlerblog.com/2011/07/08/changing-the-wp_mail-from-address-in-wordpress-without-a-plugin