script in root of WP
<?php // Set $to as the email you want to send the test to. $to = "you@yourdomain.com" ; // No need to make changes below this line. // Email subject and body text. $subject = ' wp_mail function test ' ; $message = ' This is a test of the wp_mail function: wp_mail is working ' ; $headers = '' ; // Load WP components, no themes. define ('WP_USE_THEMES', false); require('wp-load.php'); // send test message using wp_mail function. $sent_message = wp_mail( $to, $subject, $message, $headers); //display message based on the result. if ( $sent_message ) { // The message was sent. echo 'The test message was sent. Check your email inbox.' ; } else { // The message was not sent. echo 'The message was not sent!' ; }
http://www.butlerblog.com/2011/07/08/changing-the-wp_mail-from-address-in-wordpress-without-a-plugin